Structural, Spectroscopic and Thermal Characterisation of bis (dibenzoylmethanato)Cd(II) Adducts with Dimethylsulfoxide and Water (CROSBI ID 145172)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Halasz, Ivan ; Horvat, Michaela ; Biljan, Tomislav ; Meštrović, Ernest
engleski
Structural, Spectroscopic and Thermal Characterisation of bis (dibenzoylmethanato)Cd(II) Adducts with Dimethylsulfoxide and Water
Adducts of cadmium(II) dibenzoylmethate, Cd(dbm)2X2 (X = DMSO, H2O) were synthesized and analyzed by thermogravimetric analysis (TGA), differential-scanning calorimetry (DSC), hot-stage microscopy (HSM), single crystal X-ray diffraction, FTIR and Raman spectroscopy, and elemental analysis. Products obtained by thermal decomposition of the two Cd(II) complexes in oxygen, were used for quantitative analysis of cadmium in the adduct molecules. Single-crystal X-ray diffraction analysis of the DMSO adduct revealed that it has cis configuration. The DMSO adduct crystallizes in P21/a space group, a = 17.2494(6) Å ; ; ; , b = 8.3251(4) Å ; ; ; , c = 22.2746(9) Å ; ; ; , β = 93.836(3)°, V = 3191.53(7) Å ; ; ; 3, Z = 4.
Hot-stage microscopy ; Thermogravimetric analysis ; Differential scanning calorimetry ; FTIR spectroscopy ; Raman spectroscopy ; Adduct ; Cadmium(II) ; β -diketone
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Podaci o izdanju
38 (10)
2008.
793-800
objavljeno
1074-1542
1572-8854
10.1007/s10870-008-9392-0