Synthesis and Characterization of Dicyclopalladated Complexes of Azobenzene Derivatives by Experimental and Computational Methods (CROSBI ID 145153)
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Babić, Darko ; Ćurić, Manda ; Molčanov, Krešimir ; Ilc, Gregor ; Plavec, Janez
engleski
Synthesis and Characterization of Dicyclopalladated Complexes of Azobenzene Derivatives by Experimental and Computational Methods
Synthesis and properties of new dicyclopalladated azobenzenes with different solvent molecules as ancillary ligands (dmf, dmso and py) are reported. Crystal structures of five new complexes are presented and discussed. Quantum chemical calculations were used to rationalize cis/trans isomerism exhibited by varying the solvent ligand, aromaticity of palladacycles and UV-vis photoabsorption spectra.
cyclopalladation ; azobenzenes ; cis/trans isomerism ; aromaticity ; nucleus independent chemical shift ; quantum chemical calculations ; time dependent DFT
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