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Pregled bibliografske jedinice broj: 36668

On the assembling of fullerenes from cyclocarbons


Babić, Darko; Trinajstić, Nenad
On the assembling of fullerenes from cyclocarbons // Journal of molecular structure, 376 (1996), 1-2; 507-511 doi:10.1016/0022-2860(95)09085-1 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 36668 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
On the assembling of fullerenes from cyclocarbons

Autori
Babić, Darko ; Trinajstić, Nenad

Izvornik
Journal of molecular structure (0022-2860) 376 (1996), 1-2; 507-511

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
fullerene ; cyclocarbon oxides ; carbocycles

Sažetak
A simple mechanism for fullerene formation has been postulated, based on the experimental results from mass spectrometry of cyclocarbon oxides. According to the hypothesis, cyclocarbons are only cross-bonded, without any bond being broken. In order to explain the formation of C70 fullerene from C18 and C24 carbocycles, a particular C72 isomer has been assumed as an intermediate, which decomposes into C70 by C2 loss. A combinatorial analysis showed that the particular C72 isomer can be assembled from three C24 carbocycles by formation of additional bonds between and inside the cycles, in six different ways. However, there is no single way to achieve this from four C18 carbocycles. The results show that a more complex rearrangement must be involved in the formation of C70 under the given conditions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
00980606

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Darko Babić (autor)

Avatar Url Nenad Trinajstić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com

Citiraj ovu publikaciju:

Babić, Darko; Trinajstić, Nenad
On the assembling of fullerenes from cyclocarbons // Journal of molecular structure, 376 (1996), 1-2; 507-511 doi:10.1016/0022-2860(95)09085-1 (međunarodna recenzija, članak, znanstveni)
Babić, D. & Trinajstić, N. (1996) On the assembling of fullerenes from cyclocarbons. Journal of molecular structure, 376 (1-2), 507-511 doi:10.1016/0022-2860(95)09085-1.
@article{article, year = {1996}, pages = {507-511}, DOI = {10.1016/0022-2860(95)09085-1}, keywords = {fullerene, cyclocarbon oxides, carbocycles}, journal = {Journal of molecular structure}, doi = {10.1016/0022-2860(95)09085-1}, volume = {376}, number = {1-2}, issn = {0022-2860}, title = {On the assembling of fullerenes from cyclocarbons}, keyword = {fullerene, cyclocarbon oxides, carbocycles} }
@article{article, year = {1996}, pages = {507-511}, DOI = {10.1016/0022-2860(95)09085-1}, keywords = {fullerene, cyclocarbon oxides, carbocycles}, journal = {Journal of molecular structure}, doi = {10.1016/0022-2860(95)09085-1}, volume = {376}, number = {1-2}, issn = {0022-2860}, title = {On the assembling of fullerenes from cyclocarbons}, keyword = {fullerene, cyclocarbon oxides, carbocycles} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati:





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