Solid state vs. solution photochemistry of N-(2-adamantyl)phthalimide (CROSBI ID 541153)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Basaric, Nikola ; Horvat, Margareta ; Mlinarić-Majerski, Kata ; Neudörfl, Jörg ; Griesbeck, G. Axel
engleski
Solid state vs. solution photochemistry of N-(2-adamantyl)phthalimide
Photochemistry in the solid state has attracted considerable attention in last decades. The main interest for caring out photoreactions in the solid state is stereoselectivity which can not be attained in the solution phase. Besides, crystals provide ideal environments for studying the structure-reactivity relationship. In the scope of our research on the photochemistry of adamantane-phthalimides we turned our attention to photoreactions in the solid state. We discovered that photoreaction of N-(2-adamantyl)phthalimide in solution gives products with exo-alcohol prevailing in the photolysis mixture. On the other hand in the solid state, photochemical reaction is selective giving the endo-alcohol. The reason for the different selectivity of the reaction in the solution and the solid state will be discussed.
adamantane; H-abstraction; phthalimide; photochemistry
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Podaci o prilogu
405-405.
2008.
objavljeno
Podaci o matičnoj publikaciji
XXIInd IUPAC Symposium on Photochemistry
Gothenburg:
Podaci o skupu
XXIInd IUPAC Symposium on Photochemistry
poster
28.07.2008-01.08.2008
Göteborg, Švedska