engleski

Photoelectron spectra of some organozinc compounds

The electronic structures of bis(pentafluorophenyl)zinc (I) and dichloro(N, N, N0, N0-tetramethylethylenediamine) zinc(II) (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and DFT/ OVGF calculations. We discuss the properties of Zn-aryl and Zn– N bonds on the basis of spectroscopic evidence i.e. the nature of metal– ligand bonding. Our study is the first reported one on the photoelectron spectra of zinc-aryl complex.

organozinc compounds ; uv photoelectron spectra ; metalloenzymes

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