PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity (CROSBI ID 141221)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Vuina, Daniela ; Pilepić, Viktor ; Ljubas, Daniel ; Sanković, Krešimir ; Sajenko, Ivana ; Uršić, Stanko
engleski
PCET in the Oxidation of Ascorbate. Dramatic Change of the Kinetic Isotope Effect on the Change in Solvent Polarity
The first step of the oxydation of ascorbate with substituted nitrosobenzenes is a proton-coupled electron transfer (PCET) reaction and the observed kinetic isotope effects in the reaction, kH2O/kD2O, change dramatically with the change in solvent polarity, in line with the known theoretical predictions.
proton-coupled electron transfer; kinetic isotope effects; ascorbate
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
