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Flexible supramolecular ring-like host for various tetrahedral anion guests


Dubravka Matković-Čalogović, Krunoslav Užarević, Ivica Đilović, Marina Cindrić
Flexible supramolecular ring-like host for various tetrahedral anion guests // Book of Abstracts, 24th European Crystallographic Meeting, ECM24 / Nouzha Bouhmaida, Mohamed El Azhari, Laila Oualal, Siham Rezzouqui, Abdelmalek Thalal (ur.).
Marrakech, Maroko, 2007. str. 173-173 (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
Flexible supramolecular ring-like host for various tetrahedral anion guests

Autori
Dubravka Matković-Čalogović, Krunoslav Užarević, Ivica Đilović, Marina Cindrić

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of Abstracts, 24th European Crystallographic Meeting, ECM24 / Nouzha Bouhmaida, Mohamed El Azhari, Laila Oualal, Siham Rezzouqui, Abdelmalek Thalal - Marrakech, Maroko, 2007, 173-173

Skup
24th European Crystallographic Meeting, ECM24

Mjesto i datum
Marrakech, Maroko, 22-27.08.2007

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Supramolecular receptor; anion binding; hydrogen bond

Sažetak
Anion binding by synthetic receptors is a rapidly growing area of interest in supramolecular chemistry. Such research enables better understanding of the role of anion binding in biological systems. The design of anion receptors is challenging. Anions can be pH sensitive, complex anions can have different geometries. Therefore, anion receptors must function in active pH range of anions. Also, it is optimal for the receptors to have flexible geometry and so become complementary to various anion guests. In our work, we prepared a supramolecular host for two tetrahedral anions: SO42- and ClO4-. The crystals are unstable upon exposure to air so the single crystal diffraction data were collected from the crystal mounted in a loop in a mixture of methanol and glycerol, and cooled in nitrogen vapour stream at 100 K. The structures revealed that the ring-like host is formed by three molecules which have flexible parts. When sulphate anion is the guest it occupies the center of the ring since the hydrophilic parts of the molecules are at the inside of the formed host ring. The disordered sulphate anion forms 12 hydrogen bonds with the host molecules. On contrary, when perchlorate anion is the guest it occupies voids between the rings formed by three molecules which are now folded in such a way that the methyl groups point inward leaving no space within the ring for the guest.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
119-1191342-1082 - Novi kompleksni spojevi i materijali-kemijski i biološki katalizatori (Marina Cindrić, )
119-1193079-1084 - Strukturno istraživanje bioloških makromolekula metodom rentgenske difrakcije (Dubravka Matković-Čalogović, )

Ustanove
Prirodoslovno-matematički fakultet, Zagreb