engleski

Formation of hydroxamic acids promoted by metal ions. interaction of aldehyde carbonyl group with C-nitroso group in the presence of ferric ions

Formation of N-phenyl substituted hydroxamic acids in the reaction of formaldehyde with substituted mtrosobenzene is strongly catalysed by Fe3+ ions, which stabilize the transition state for the rate-controlling proton transfer from the carbon of nitrosocarbinolic cation intermediate leading to the product, hydroxamic acid

hydroxamic acid ; metal ion catalysis ; nitroso ; aldehyde

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