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TLC with Densitometry in Waste Minimisation


Koprivanac, Natalija; Lazarević, Zvjezdana; Lončarić-Božić, Ana; Papić, Sanja; Balenović, Jadranka
TLC with Densitometry in Waste Minimisation // Book of Abstracts ISC'98, 22nd International Symposium on Chromatography / Liberti, A. ; Dondi, F. (ur.).
Roma: Universita di Roma La Sapienza, 1998. (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
TLC with Densitometry in Waste Minimisation

Autori
Koprivanac, Natalija ; Lazarević, Zvjezdana ; Lončarić-Božić, Ana ; Papić, Sanja ; Balenović, Jadranka

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of Abstracts ISC'98, 22nd International Symposium on Chromatography / Liberti, A. ; Dondi, F. - Roma : Universita di Roma La Sapienza, 1998

Skup
22nd International Symposium on Chromatography

Mjesto i datum
Rim, Italij, 13-18. 09.1998.

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Waste minimisation; reactive dye; densitometry

Sažetak
Waste minimization and cleaner production policy are become a decisive factor of the process design allowing potential environmental problem to be avoided rather than remediated. The pollution of wastewater as well as the production costs could be significantly decreased by optimization of process (1). Reactive dye production wastewater is strongly coloured due to the high solubility of this type of dyes as well as the presence of certain amount of coloured unreacted raw materials and by-products. The manufacturing process of monochlorotriazine reactive dye was studied using the certain anthraquinone reactive blue as a model. TLC technic for separation of raw materials, structurally related intermediates and products was used. A series of 12 chromatographic systems has been evaluated using chemometry, and has been established that the most favorable mobile phase for TLC of the investigated compounds is chloroform : isopropyl alcohol : ammonium hydroxide ( 2 : 4 : 1 ) (2). The two step synthesis process monitored using TLC with densitometry resulted in decreased wastewater pollution due to the process optimization.(1) D.T. Allen and K.S. Rosselot, Pollution Prevention for Chemical Processes, John Wiley & Sons, Inc. New York, 1996.(2) Z. Lazarević, M. Medić Šarić, N. Koprivanac, A. Lončarić Božić and S. Papić, InCom'98, International Symposium on Instrumentalized Analytical Chemistry and Computer Technology, (1998) 178.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo



POVEZANOST RADA


Projekt / tema
125018

Ustanove
Fakultet kemijskog inženjerstva i tehnologije, Zagreb