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Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog


Kirin, Srećko I.; Ohr, Kristi; Yennawar, Hemant P.; Morgan, Christopher M.; Levine, Lauren A.; Williams, Mary Elizabeth
Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog // Inorganic Chemistry Communications, 10 (2007), 6; 652-656 (međunarodna recenzija, članak, znanstveni)


Naslov
Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog

Autori
Kirin, Srećko I. ; Ohr, Kristi ; Yennawar, Hemant P. ; Morgan, Christopher M. ; Levine, Lauren A. ; Williams, Mary Elizabeth

Izvornik
Inorganic Chemistry Communications (1387-7003) 10 (2007), 6; 652-656

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Artificial peptide; bioinorganic chemistry; coordination polymer; Cu(II) complex; nucleic acid analog; X-ray

Sažetak
The inorganic nucleoside analog [Boc-aeg{; ; Cu(pda)py-Ac}; ; -OMe] (3) is prepared and fully characterized. The X-ray single crystal analysis reveals that 3 assembles by apical Cu– O bonds into a coordination polymer, with short Cu– Cu distances of 5.32 and 5.78 &Aring ; . The solid state structure of 3 is in accordance with an isotactic structural model for charge neutral inorganic nucleic acids analogs. Aeg = (2-aminoethyl)glycine, py-Ac = 4-acetyl pyridine, pda = pyridine-2, 6-dicarboxylic acid.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Autor s matičnim brojem:
Srećko Kirin, (192540)

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus