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Pregled bibliografske jedinice broj: 314141

Carbenes in polycyclic systems: generation and fate of potential adamantane-1, 3-dicarbenes


Klaić, Lada; Alešković, Marija; Veljković, Jelena; Mlinarić-Majerski, Kata
Carbenes in polycyclic systems: generation and fate of potential adamantane-1, 3-dicarbenes // Journal of physical organic chemistry, 21 (2008), 4; 299-305 doi:10.1002/poc.1319 (međunarodna recenzija, članak, znanstveni)


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Naslov
Carbenes in polycyclic systems: generation and fate of potential adamantane-1, 3-dicarbenes

Autori
Klaić, Lada ; Alešković, Marija ; Veljković, Jelena ; Mlinarić-Majerski, Kata

Izvornik
Journal of physical organic chemistry (0894-3230) 21 (2008), 4; 299-305

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
carbenes; polycyclic compounds; dicarbenes; azines; adamantane

Sažetak
Potential formation and reactions of adamantane-1, 3-dicarbenes 1-3 generated under different conditions and from different precursors, such as sodium salt of adamantane-1, 3-dicarbaldehyde ditosylhydrazone (4a), sodium salt of 1, 3-diacetyladamantane ditosylhydrazone (5a), sodium salt of 1, 3-dibenzoyladamantane ditosylhydrazone (6a) and 1, 3-bis(diazobenzyl)adamantane (7) are reported. Carbene species generated thermally from 4a yielded bishomoadamantane (15), as a final product, via intramolecular insertion into adjacent C-C bond and formation of putative anti-Bredt olefin species, followed by hydrogen abstraction. Pyrolysis of the same sodium salt 4a in the presence of hydrogen donor n-Bu3SnH afforded 1, 3-dimethyladamantane (17). Thermal decomposition of sodium salt 5a afforded 1, 3-divinyladamantane (14). However, thermal decomposition of sodium salt 6a and diazo-precursor 7 gave benzonitrile as a sole identified product. On the contrary, photolysis of 7 afforded dimeric azine.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Kata Majerski, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Lada Klaić (autor)

Avatar Url Kata Majerski (autor)

Avatar Url Marija Alešković (autor)

Avatar Url Jelena Veljković (autor)

Citiraj ovu publikaciju

Klaić, Lada; Alešković, Marija; Veljković, Jelena; Mlinarić-Majerski, Kata
Carbenes in polycyclic systems: generation and fate of potential adamantane-1, 3-dicarbenes // Journal of physical organic chemistry, 21 (2008), 4; 299-305 doi:10.1002/poc.1319 (međunarodna recenzija, članak, znanstveni)
Klaić, L., Alešković, M., Veljković, J. & Mlinarić-Majerski, K. (2008) Carbenes in polycyclic systems: generation and fate of potential adamantane-1, 3-dicarbenes. Journal of physical organic chemistry, 21 (4), 299-305 doi:10.1002/poc.1319.
@article{article, year = {2008}, pages = {299-305}, DOI = {10.1002/poc.1319}, keywords = {carbenes, polycyclic compounds, dicarbenes, azines, adamantane}, journal = {Journal of physical organic chemistry}, doi = {10.1002/poc.1319}, volume = {21}, number = {4}, issn = {0894-3230}, title = {Carbenes in polycyclic systems: generation and fate of potential adamantane-1, 3-dicarbenes}, keyword = {carbenes, polycyclic compounds, dicarbenes, azines, adamantane} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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