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EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination (CROSBI ID 134303)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Novosel, Nikolina ; Žilić, Dijana ; Pajić, Damir ; Jurić, Marijana ; Perić, Berislav ; Zadro, Krešo ; Rakvin, Boris ; Planinić, Pavica EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination // Solid state sciences, 10 (2008), 10; 1387-1394. doi: 10.1016/j.solidstatesciences.2008.01.021

Podaci o odgovornosti

Novosel, Nikolina ; Žilić, Dijana ; Pajić, Damir ; Jurić, Marijana ; Perić, Berislav ; Zadro, Krešo ; Rakvin, Boris ; Planinić, Pavica

engleski

EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination

Magnetic properties of single crystals of the heterometallic complex [Cu(bpy)3]2[Cr(C2O4)3]NO3 9H2O (bpy = 2, 2'-bipyridine)have been investigated. From the recorded EPR spectra, the spin-Hamiltonian parameters have been determined. The magnetization measurements have shown magnetic anisotropy at low temperatures, which has been analysed as a result of the zero-field splitting of the CrIII ion. By fitting the exactly derived magnetization expression to the measured magnetization data, the axial zero-field splitting parameter, D, has been calculated. Comparing to the EPR measurements, it has been confirmed that D can be determined from the measurements of the macroscopic magnetization on the single crystals.

heterometallic complex; zero-field splitting; EPR; magnetization

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Podaci o izdanju

10 (10)

2008.

1387-1394

objavljeno

1293-2558

10.1016/j.solidstatesciences.2008.01.021

Povezanost rada

Fizika, Kemija

Poveznice
Indeksiranost