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Photoelectron Spectra and Electronic Structure of Diazidirines

The Hel photoelectron (PE) spectra of tetramethyldiaziridine (1), l-methyl-3, 3-cyclohexylidenediaziridine (2), 2-isopropyl-3.3-dimethyldiaziridine (3), l-benzyl-3, 3-dimethyldiaziridine (4), l-benzyil-3, 3-cyclohexylidenediaziridine (5), l-(p-methoxybenzyl)-3, 3-dimethydiaziridine (6), l-benzyl-2, 3, 3-trimethyl-diaziridine (7), 2, 3-dimethyl-3-benzyldiaziridine (8), l, 2, 3-trimethyl-3-benzyldiaziridine (9), 3, 3-dibenzyldiaziridine (10), and l-methyl-3, 3-dibenzyldiaziridine (ll) were recorded and theer electronic structure determined on the basis of ab initio calculations for diaziridine and spectra comparison using the composite molecule method.

diaziridine; photoelectron (PE) spectra

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