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Pregled bibliografske jedinice broj: 293999

Copolymerization of N-tert-Butylacrylamide with Ethylene Glycol Dimethacrylate


Erceg Kuzmić, Ana; Bogdanić, Grozdana; Vuković, Radivoje
Copolymerization of N-tert-Butylacrylamide with Ethylene Glycol Dimethacrylate // Journal of Macromolecular Science. Part A, 44 (2007), 7; 721-725 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 293999 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Copolymerization of N-tert-Butylacrylamide with Ethylene Glycol Dimethacrylate

Autori
Erceg Kuzmić, Ana ; Bogdanić, Grozdana ; Vuković, Radivoje

Izvornik
Journal of Macromolecular Science. Part A (1060-1325) 44 (2007), 7; 721-725

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
N-tert-butylacrylamide; ethylene glycol dimethacrylate; copolymerization; model compound

Sažetak
N-tert-butylacrylamide (NtBA) was copolymerized with ethylene glycol dimethacrylate (EDMA) in butanone solution using dibenzoyl peroxide (Bz2O2) as a free-radical initiator over a wide composition and conversion range. The copolymer composition was determined from nitrogen content. Taking into consideration a low conversion value in the copolymerization reaction (to 20 %), monomer reactivity ratios were estimated using the Kelen-Tüdos graphical method, and were found to be r1=0.26 (NtBA) and r2=7.05 (EDMA). In order to get a better insight into the mechanism of nanoporous copolymers of NtBA with EDMA preparation by thermal degradation of copolymers of N-acryl-N, N'-di-tert-butylurea (A-DitBuU) with EDMA, nonporous copolymers (model compound) of the same chemical structure and composition were prepared by performing copolymerization of NtBA with EDMA up to the high conversion of 97-100 %. Thermal behavior of nanoporous and nonporous copolymers of NtBA with EDMA was studied.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo



POVEZANOST RADA


Projekti:
0061001
061-0000000-3029 - NOVA TEHNOLOGIJA DOBIVANJA MOLEKULSKI TISKANIH POLIMERNIH MATERIJALA (Erceg Kuzmić, Ana, MZOS ) ( POIROT)

Ustanove:
INA-Industrija nafte d.d.

Citiraj ovu publikaciju

Erceg Kuzmić, Ana; Bogdanić, Grozdana; Vuković, Radivoje
Copolymerization of N-tert-Butylacrylamide with Ethylene Glycol Dimethacrylate // Journal of Macromolecular Science. Part A, 44 (2007), 7; 721-725 (međunarodna recenzija, članak, znanstveni)
Erceg Kuzmić, A., Bogdanić, G. & Vuković, R. (2007) Copolymerization of N-tert-Butylacrylamide with Ethylene Glycol Dimethacrylate. Journal of Macromolecular Science. Part A, 44 (7), 721-725.
@article{article, year = {2007}, pages = {721-725}, keywords = {N-tert-butylacrylamide, ethylene glycol dimethacrylate, copolymerization, model compound}, journal = {Journal of Macromolecular Science. Part A}, volume = {44}, number = {7}, issn = {1060-1325}, title = {Copolymerization of N-tert-Butylacrylamide with Ethylene Glycol Dimethacrylate}, keyword = {N-tert-butylacrylamide, ethylene glycol dimethacrylate, copolymerization, model compound} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus





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