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Pregled bibliografske jedinice broj: 261722

Synthesis of new Triguanide Derivatives


Štrukil, Vjekoslav; Glasovac, Zoran; Eckert-Maksić, Mirjana
Synthesis of new Triguanide Derivatives // 1st European Chemistry Congress : Abstract book / Horvai, Gyorgy (ur.).
Budapest: Hungarian Chemical Society, 2006. str. 343-344 (poster, međunarodna recenzija, sažetak, znanstveni)


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Naslov
Synthesis of new Triguanide Derivatives

Autori
Štrukil, Vjekoslav ; Glasovac, Zoran ; Eckert-Maksić, Mirjana

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
1st European Chemistry Congress : Abstract book / Horvai, Gyorgy - Budapest : Hungarian Chemical Society, 2006, 343-344

Skup
European Chemistry Congress (1 ; 2006)

Mjesto i datum
Budimpešta, Mađarska, 27.-31.08.2006

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
triguanide; basicity; DFT calculations

Sažetak
Synthesis of polyguanides is of considerable interest because of, inter alia, their outstanding basicity.[1, 2] Particullary interesting in this regard are branched polyguanides and guanidines possesing substituents capable of forming intramolecular hydrogen bonds.[2] Typical example is provided by N1, N2, N6, N7-tetraisopropyl-N4-dimethylamoniopropyl-triguanid-N4-ium sulphate (1), synthesis of which will be presented in this communication. 1 was obtained by one-pot synthesis starting from N-(3-dimethylaminopropyl)-guanidine and diisopropylcarbodiimide. The structure of the resulting triguanide was elucidated by X-ray analysis of the corresponding sulphate salt. [3] The effect of various substituents at the reactants and reaction temperature on the outcome of reaction will be discussed in detail. In addition, a brief overview of the effect of substituents on proton affinities, based on results of DFT (B3LYP/6-311+G(2d, p)//HF/6-31G**) calculations will be given.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
0098056

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Mirjana Maksić (autor)

Avatar Url Zoran Glasovac (autor)

Avatar Url Vjekoslav Štrukil (autor)


Citiraj ovu publikaciju:

Štrukil, Vjekoslav; Glasovac, Zoran; Eckert-Maksić, Mirjana
Synthesis of new Triguanide Derivatives // 1st European Chemistry Congress : Abstract book / Horvai, Gyorgy (ur.).
Budapest: Hungarian Chemical Society, 2006. str. 343-344 (poster, međunarodna recenzija, sažetak, znanstveni)
Štrukil, V., Glasovac, Z. & Eckert-Maksić, M. (2006) Synthesis of new Triguanide Derivatives. U: Horvai, G. (ur.)1st European Chemistry Congress : Abstract book.
@article{article, editor = {Horvai, G.}, year = {2006}, pages = {343-344}, keywords = {triguanide, basicity, DFT calculations}, title = {Synthesis of new Triguanide Derivatives}, keyword = {triguanide, basicity, DFT calculations}, publisher = {Hungarian Chemical Society}, publisherplace = {Budimpe\v{s}ta, Ma\djarska} }
@article{article, editor = {Horvai, G.}, year = {2006}, pages = {343-344}, keywords = {triguanide, basicity, DFT calculations}, title = {Synthesis of new Triguanide Derivatives}, keyword = {triguanide, basicity, DFT calculations}, publisher = {Hungarian Chemical Society}, publisherplace = {Budimpe\v{s}ta, Ma\djarska} }




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