engleski

2,4-dimethylmethano-2,4-didehydroadamantane and its reactivity in relation to the unsubstituted analogue

2, 4-Dimethylmethano-2, 4-didehydroadamantane (1) has been prepared and the gem-dimethyl substituent effects of propellane 1 in relation to its unsubstituted analogue 2 were studied. The reactivity of 1 is considerably greater than that of 2 due to higher nucleophilicity of its central bond. However, 1 is thermally more stable than 2.

gem-dimethyl ; propellane ; unsubstituted analogue ; 2, 4-Dimethylmethano-2, 4-didehydroadamantane

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