Theory of irreversible electrode reactions coupled to ion transfer across the liquid / liquid interface (CROSBI ID 124618)
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Podaci o odgovornosti
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
engleski
Theory of irreversible electrode reactions coupled to ion transfer across the liquid / liquid interface
Kinetically controlled electro-oxidation of a redox probe dissolved in the organic solvent, which is interposed between an electrode surface and an aqueous solution as a thin layer, is analyzed theoretically. It is demonstrated that the electrode reaction rate constant can be measured by the variation of scan rate in linear scan voltammetry both in the absence and in the superfluity of the supporting electrolyte dissolved in the film.
Kinetics of electrode reaction; liquid / liquid interface; coupled electron and ion transfers.
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