Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 252768

Synthesis of N-Acryl-N, N’ -di-tert-Butylurea and Copolymerization with Ethylene Glycol Dimethacrylate


Erceg Kuzmić, Ana; Podolski, Štefica; Bogdanić, Grozdana; Vuković, Radivoje
Synthesis of N-Acryl-N, N’ -di-tert-Butylurea and Copolymerization with Ethylene Glycol Dimethacrylate // Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 43 (2006), 6; 879-887 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 252768 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Synthesis of N-Acryl-N, N’ -di-tert-Butylurea and Copolymerization with Ethylene Glycol Dimethacrylate

Autori
Erceg Kuzmić, Ana ; Podolski, Štefica ; Bogdanić, Grozdana ; Vuković, Radivoje

Izvornik
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry (1060-1325) 43 (2006), 6; 879-887

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
N-acryl-N; N’ -di-tert-butylurea; poly(N-acryl-N; N’ -di-tert-butylurea-co-ethylene glycol dimethacrylate); thermal degradation; tert-butylisocyanate; poly(N-acryl-N-terc-butylamide-co-ethylene glycol dimethacrylate)

Sažetak
Synthesis and free-radical initiated copolymerization of N-acryl-N, N’ -di-tert-butylurea (A-DitBuU) with ethylene glycol dimethacrylate (EDMA) are described. The A-DitBuU monomer was prepared by the condensation of acrylic acid to the N, N’ -di-tert-butylcarbodiimide (DitBuC) at room temperature. Copolymers of A-DitBuU with EDMA of different monomer to monomer ratios in the feed were prepared in the presence of dibenzoyl peroxide (Bz2O2) in butanone at 70°C for 48 h up to a high conversion. The obtained crosslinked copolymers are insoluble in organic solvents. Copolymers thermal decomposition resulted in separation of tert-butylisocyanate (C4H9NCO) in the temperature range between 180 and 280°C and by the formation of the thermally stable molecularly imprinted copolymers of N-acryl-N-terc-butylamide (A-tBuA) with EDMA.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
0061001

Ustanove:
INA-Industrija nafte d.d.

Citiraj ovu publikaciju

Erceg Kuzmić, Ana; Podolski, Štefica; Bogdanić, Grozdana; Vuković, Radivoje
Synthesis of N-Acryl-N, N’ -di-tert-Butylurea and Copolymerization with Ethylene Glycol Dimethacrylate // Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 43 (2006), 6; 879-887 (međunarodna recenzija, članak, znanstveni)
Erceg Kuzmić, A., Podolski, Š., Bogdanić, G. & Vuković, R. (2006) Synthesis of N-Acryl-N, N’ -di-tert-Butylurea and Copolymerization with Ethylene Glycol Dimethacrylate. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 43 (6), 879-887.
@article{article, year = {2006}, pages = {879-887}, keywords = {N-acryl-N, N and \#8217, -di-tert-butylurea, poly(N-acryl-N, N and \#8217, -di-tert-butylurea-co-ethylene glycol dimethacrylate), thermal degradation, tert-butylisocyanate, poly(N-acryl-N-terc-butylamide-co-ethylene glycol dimethacrylate)}, journal = {Journal of Macromolecular Science, Part A: Pure and Applied Chemistry}, volume = {43}, number = {6}, issn = {1060-1325}, title = {Synthesis of N-Acryl-N, N and \#8217; -di-tert-Butylurea and Copolymerization with Ethylene Glycol Dimethacrylate}, keyword = {N-acryl-N, N and \#8217, -di-tert-butylurea, poly(N-acryl-N, N and \#8217, -di-tert-butylurea-co-ethylene glycol dimethacrylate), thermal degradation, tert-butylisocyanate, poly(N-acryl-N-terc-butylamide-co-ethylene glycol dimethacrylate)} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus





Contrast
Increase Font
Decrease Font
Dyslexic Font