engleski

Esterase catalyzed regioselective hydrolyses of acetylated monosaccharides

Deacylations of fully acylated D-glucopyranoses, methyl D-glucopyranosides and 2-acetamido-2-deoxy-D-glucopyranosides catalyzed by rabbit serum or the esterase isolated from rabbit serum were investigated. Depending on the structure of the acyl protecting group a high degree of regioselectivity is observed. Products of enzymic hydrolysis followed by intramolecular migrations of acetyl groups are also described.

serum esterses ; hydrolyses of acetylated monosaccharides ; acylated D-glucopyranose

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