engleski

Synthesis of 7-silanorbornene electron donor-acceptor polycyclic dyads

Organometallic compounds, particularly those with metal-metal s-bonds as electron-rich species are excellent electron donors. Studies with group-14 elements (silicon and germanium) catenanes showed electron transfer to electron acceptor. Furthermore, it was shown that C60 is good electron aceptor for photoinduced electron transfer from cyclic organogermanium or organosilicon ' compounds. Preparation of electron-transfer dyads (donor-acceptor molecules) with novel molecular architectures and ED/EA geometrical orientations is the current synthetic challenge.

cycloaddition; electron transfer; norbornenes; high pressure

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