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izvor podataka: crosbi

Synthetic approaches to bis-peptides attached on polynorbornane molecular scaffolds with well-defined relative positions and distances (CROSBI ID 515274)

Prilog sa skupa u zborniku | izvorni znanstveni rad | međunarodna recenzija

Shang, Muhong ; Warrener, Ronald N. ; Butler, Douglas, N. ; Margetić, Davor Synthetic approaches to bis-peptides attached on polynorbornane molecular scaffolds with well-defined relative positions and distances // Proceedings of ECSOC-9 : The Ninth International Electronic Conference on Synthetic Organic Chemistry. Basel: MDPI Books, 2005

Podaci o odgovornosti

Shang, Muhong ; Warrener, Ronald N. ; Butler, Douglas, N. ; Margetić, Davor

engleski

Synthetic approaches to bis-peptides attached on polynorbornane molecular scaffolds with well-defined relative positions and distances

This paper describes novel synthetic approaches to polynorbornane molecular scaffolds substituted with peptides at various, well-defined positions. A library of norbornene building blocks with attached peptides was prepared. Alkene cyclobutane epoxide (ACE) coupling method was used as a key step reaction for connecting of two norbornene building blocks into bis-peptide scaffolds. Photodimerization of cyclobutene diesters offers alternative route to polynorbornane bis-peptides. Pyrrolo-peptides were used for preparation of peptide substituted 7-aza norbornenes. Unsymmetrical bis-peptide scaffolds were prepared by ACE coupling of peptide-norbornane epoxide with another norbornene-peptide block. Chemical elaboration of bridgehead dimethyl esters of ACE products or epoxide ACE reagents was also used for peptide attachment.

norbornene; peptides; cycloadditions

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Podaci o prilogu

2005.

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objavljeno

3-906980-16-2

Podaci o matičnoj publikaciji

Proceedings of ECSOC-9 : The Ninth International Electronic Conference on Synthetic Organic Chemistry

Basel: MDPI Books

Podaci o skupu

9th International Electronic Conference on Synthetic Organic Chemistry : ECSOC-9

poster

30.10.2005-30.10.2005

online

Povezanost rada

Kemija