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Probabilistic kinetic model of slow oxidation of low-density lipoprotein III. Hydroperoxide-free initiation (CROSBI ID 121203)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Krilov, Dubravka ; Herak, Janko N. Probabilistic kinetic model of slow oxidation of low-density lipoprotein III. Hydroperoxide-free initiation // Journal of chemical information and computer sciences, 45 (2005), 6; 1616-1620

Podaci o odgovornosti

Krilov, Dubravka ; Herak, Janko N.

engleski

Probabilistic kinetic model of slow oxidation of low-density lipoprotein III. Hydroperoxide-free initiation

Theoretical model is presented that explains slow copper-induced oxidation of low-density lipoprotein in the systems free of seeded hydroperoxydes. The model is based on the probabilistic kinetic theory, modified to take into account different radical generation rates by oxidized and reduced forms of the metal ions. It is shown that the initiation and progression of the LDL oxidation can take place in any LDL dispersion by metal-induced oxidation of  -tocopherol, one of the constituents of LDL, and formation of slowly reacting  -tocopheroxyl radical. Selected values of several adjustable parameters define actual temporal profiles of the quantities defining the oxidation process

atherosclerosis; LDL; oxidation; seeded hydroperoxides; tocopherol-mediated peroxidation

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Podaci o izdanju

45 (6)

2005.

1616-1620

objavljeno

0095-2338

Povezanost rada

Fizika, Kemija, Biologija