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Pregled bibliografske jedinice broj: 210241

Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis


Cetina-Čižmek, Biserka; Vodopija Mandić, Snježana; Ašperger, Smiljko
Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis // Croatica chemica acta, 78 (2005), 1; 129-132 (međunarodna recenzija, članak, znanstveni)


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Naslov
Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis

Autori
Cetina-Čižmek, Biserka ; Vodopija Mandić, Snježana ; Ašperger, Smiljko

Izvornik
Croatica chemica acta (0011-1643) 78 (2005), 1; 129-132

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
ferrocenyl esters solvolyses; acid catalyzed solvolyses; formolysis and acetolysis; ferrocenylmethyl benzoate; solvent separated ion pairs

Sažetak
The formolysis and acetolysis of ferrocenylmethyl benzoate are proton catalyzed and accelerated by addition of perchloric acid. Our earlier experiments have shown that at a temperature of about 20 °C addition of a common benzoate ion in formolysis of 3.2 x 10– 4 mol dm– 3 ferrocenylmethyl benzoate suppresses the formolysis rate only slightly but the formolysis is significantly slower at 40 °C. Such rate lowering is not observed in acetolysis of the same substrate. Decrease of the formolysis rate at increased temperatures (20– 40 °C) is most probably caused by the decrease of the hydrogen ion concentration, because the stronger formic acid displaces the weaker benzoic acid from sodium benzoate, thus reducing the formic acid concentration in this acid-catalyzed system. This, however, does not occur in the weaker acetic acid. Besides, the acetolysis rates are equal in the presence of 0.1 and 0.2 mol dm– 3 sodium benzoate, while the formolysis rates decrease with the addition of benzoate. The strong temperature dependence of the formolysis rates is probably connected with the formation of formic acid dimers and the temperature dependent hydrogen bonding. Hydrogen bonding and the dimer formation in acetic acid are less pronounced than in formic acid.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
0101026

Ustanove:
Hrvatska akademija znanosti i umjetnosti


Citiraj ovu publikaciju

Cetina-Čižmek, Biserka; Vodopija Mandić, Snježana; Ašperger, Smiljko
Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis // Croatica chemica acta, 78 (2005), 1; 129-132 (međunarodna recenzija, članak, znanstveni)
Cetina-Čižmek, B., Vodopija Mandić, S. & Ašperger, S. (2005) Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis. Croatica chemica acta, 78 (1), 129-132.
@article{article, year = {2005}, pages = {129-132}, keywords = {ferrocenyl esters solvolyses, acid catalyzed solvolyses, formolysis and acetolysis, ferrocenylmethyl benzoate, solvent separated ion pairs}, journal = {Croatica chemica acta}, volume = {78}, number = {1}, issn = {0011-1643}, title = {Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis}, keyword = {ferrocenyl esters solvolyses, acid catalyzed solvolyses, formolysis and acetolysis, ferrocenylmethyl benzoate, solvent separated ion pairs} }
@article{article, year = {2005}, pages = {129-132}, keywords = {ferrocenyl esters solvolyses, acid catalyzed solvolyses, formolysis and acetolysis, ferrocenylmethyl benzoate, solvent separated ion pairs}, journal = {Croatica chemica acta}, volume = {78}, number = {1}, issn = {0011-1643}, title = {Mechanism of ferrocenylmethyl benzoate formolysis and acetolysis}, keyword = {ferrocenyl esters solvolyses, acid catalyzed solvolyses, formolysis and acetolysis, ferrocenylmethyl benzoate, solvent separated ion pairs} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Uključenost u ostale bibliografske baze podataka:


  • Chemical Abstracts





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