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Pregled bibliografske jedinice broj: 1942

Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers


Smrečki, Vilko; Baranović, Goran; Keresztury, Gabor; Meić, Zlatko
Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers // Journal of molecular structure, 408 (1997), 405-408 (međunarodna recenzija, članak, znanstveni)


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Naslov
Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers

Autori
Smrečki, Vilko ; Baranović, Goran ; Keresztury, Gabor ; Meić, Zlatko

Izvornik
Journal of molecular structure (0022-2860) 408 (1997); 405-408

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
NIR FT Raman spectra; Protonation; trans-Azobenzene

Sažetak
Near-infrared Fourier transform (NIR FT) Raman spectra of five trans-azobenzene isotopomers and their protonated and deuterated forms were recorded. Trifluoroacetic acid was found to be a good protonation agent for measuring Raman spectra of protonated azobenzene. An assignment of the most relevant vibrational modes (N=N stretching and N-H/N-H-2 in-plane bending) of the protonated and deuterated species is proposed. The N=N stretching band in irans-azobenzene isotopomers decreases by about 40 cm(-1) upon protonation, while it varies within +/- 10 cm(-1) upon deuteration with respect to the unprotonated (undeuterated) form. A comparison is made with the protonated form of the isoelectronic trans-N-benzylideneaniline.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
00980802

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Vilko Smrečki (autor)

Avatar Url Zlatko Meić (autor)

Avatar Url Goran Baranović (autor)


Citiraj ovu publikaciju

Smrečki, Vilko; Baranović, Goran; Keresztury, Gabor; Meić, Zlatko
Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers // Journal of molecular structure, 408 (1997), 405-408 (međunarodna recenzija, članak, znanstveni)
Smrečki, V., Baranović, G., Keresztury, G. & Meić, Z. (1997) Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers. Journal of molecular structure, 408, 405-408.
@article{article, year = {1997}, pages = {405-408}, keywords = {NIR FT Raman spectra, Protonation, trans-Azobenzene}, journal = {Journal of molecular structure}, volume = {408}, issn = {0022-2860}, title = {Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers}, keyword = {NIR FT Raman spectra, Protonation, trans-Azobenzene} }
@article{article, year = {1997}, pages = {405-408}, keywords = {NIR FT Raman spectra, Protonation, trans-Azobenzene}, journal = {Journal of molecular structure}, volume = {408}, issn = {0022-2860}, title = {Near-Infrared Fourier Transform Raman Spectra of Protonated and Deuterated trans-Azobenzene Isotopomers}, keyword = {NIR FT Raman spectra, Protonation, trans-Azobenzene} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus





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