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Pregled bibliografske jedinice broj: 188630

Synthesis of organometallic compounds under high pressure


Eckert-Maksić, Mirjana; Margetić, Davor; Kirin, Srećko
Synthesis of organometallic compounds under high pressure // Book of abstracts
Brijuni, 2004. (poster, nije recenziran, sažetak, ostalo)


Naslov
Synthesis of organometallic compounds under high pressure

Autori
Eckert-Maksić, Mirjana ; Margetić, Davor ; Kirin, Srećko

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, ostalo

Izvornik
Book of abstracts / - Brijuni, 2004

Skup
NATO ARW Brijuni Conference On Matter Under Extreme Conditions: Exploring Fundamental Problems In Science

Mjesto i datum
Brijuni, Hrvatska, 28.08.-03.09.2004

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
High pressure; cycloadditions; organometallics

Sažetak
High pressure synthesis of novel policyclic structures containing silicon and germanium atoms placed at the bridgehead positions, (organometallic derivatives of bicyclo(2.2.1)hept-2-ene) will be presented. Thus, 1-sila-2, 3, 4, 5-tetraphenyl-1, 1-dimethyl-2, 4-cyclopentadiene, 1-sila-2, 5-diphenyl-1, 1-dimethyl-2, 4-cyclopentadienes and 1-germa-2, 3, 4, 5-tetraphenyl-1, 1-dimethyl-2, 4-cyclopentadiene are used as reactive dienes, which readily undergo [4p+2p] cycloadditions with strained alkenes incorporated in norbornene skeleton (for instance, anti-1, 4:5, 8-diepoxy-1, 4, 5, 8-tetrahydroanthracene was used as a dienophile) to give 7-silanorbornene or 7-germanorbornadiene derivatives.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
0098147

Ustanove
Institut "Ruđer Bošković", Zagreb