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Pregled bibliografske jedinice broj: 186229

Study of Chromatographic Enantioseparation of the Esters of N-Dinitrobenzoyl (N-DNB) and N-Benzoyl (N-B) a-Amino Acids on Novel Chiral Stationary Phases Containing Structurally Matching N-DNB and N-B-a-AA Amides in the Chiral Selector


Zafirova, Biljana; Landek, Goran; Kontrec, Darko; Šunjić, Vitomir; Vinković, Vladimir
Study of Chromatographic Enantioseparation of the Esters of N-Dinitrobenzoyl (N-DNB) and N-Benzoyl (N-B) a-Amino Acids on Novel Chiral Stationary Phases Containing Structurally Matching N-DNB and N-B-a-AA Amides in the Chiral Selector // Croatica chemica acta, 77 (2004), 4; 573-579 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 186229 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Study of Chromatographic Enantioseparation of the Esters of N-Dinitrobenzoyl (N-DNB) and N-Benzoyl (N-B) a-Amino Acids on Novel Chiral Stationary Phases Containing Structurally Matching N-DNB and N-B-a-AA Amides in the Chiral Selector

Autori
Zafirova, Biljana ; Landek, Goran ; Kontrec, Darko ; Šunjić, Vitomir ; Vinković, Vladimir

Izvornik
Croatica chemica acta (0011-1643) 77 (2004), 4; 573-579

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
p-p Interactions; Chiral stationary phases; Pirkle-type; Electron-deficient groups

Sažetak
Enantioseparation ability and enantiopreference of chiral stationary phases CSP 1-3, containing terminal N-3, 5-dinitrobenzoyl (N-DNB) unit, and CSP 4, containing terminal N-benzoyl (N-B) unit are studied. Separation factors (a) for the two sets of the test racemates (TR) that structurally match chiral selector of these CSPs is determined. The first set consists of seven N-DNB a-amino acid isopropylesters (TR 1A-7A), and the second one of their N-B analogues (TR 1-7). The best enantioseparation (aaverage 1.27) is obtained when p-acceptor DNB unit is present in both, TR and CSP. One p-acceptor unit, either in analyte or in CSP, suffices for efficient enantioseparation (aaverage 1.19). Interaction between p-neutral units in the CSP and test racemate does not afford effective enantioseparation (aaverage 1.03). Using (S)-enantiomers of all TRs as the standards with CD detection has revealed regular preference of the CSPs for the enantiomers containing amino acid amide of the same absolute configuration. The possible origin of such enantiopreference is discussed

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
0098051
0098050

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Goran Landek (autor)

Avatar Url Darko Kontrec (autor)

Avatar Url Vitomir Šunjić (autor)

Avatar Url Vladimir Vinković (autor)

Citiraj ovu publikaciju

Zafirova, Biljana; Landek, Goran; Kontrec, Darko; Šunjić, Vitomir; Vinković, Vladimir
Study of Chromatographic Enantioseparation of the Esters of N-Dinitrobenzoyl (N-DNB) and N-Benzoyl (N-B) a-Amino Acids on Novel Chiral Stationary Phases Containing Structurally Matching N-DNB and N-B-a-AA Amides in the Chiral Selector // Croatica chemica acta, 77 (2004), 4; 573-579 (međunarodna recenzija, članak, znanstveni)
Zafirova, B., Landek, G., Kontrec, D., Šunjić, V. & Vinković, V. (2004) Study of Chromatographic Enantioseparation of the Esters of N-Dinitrobenzoyl (N-DNB) and N-Benzoyl (N-B) a-Amino Acids on Novel Chiral Stationary Phases Containing Structurally Matching N-DNB and N-B-a-AA Amides in the Chiral Selector. Croatica chemica acta, 77 (4), 573-579.
@article{article, year = {2004}, pages = {573-579}, keywords = {p-p Interactions, Chiral stationary phases, Pirkle-type, Electron-deficient groups}, journal = {Croatica chemica acta}, volume = {77}, number = {4}, issn = {0011-1643}, title = {Study of Chromatographic Enantioseparation of the Esters of N-Dinitrobenzoyl (N-DNB) and N-Benzoyl (N-B) a-Amino Acids on Novel Chiral Stationary Phases Containing Structurally Matching N-DNB and N-B-a-AA Amides in the Chiral Selector}, keyword = {p-p Interactions, Chiral stationary phases, Pirkle-type, Electron-deficient groups} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus





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