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Pregled bibliografske jedinice broj: 16008

Combined Biocatalytic Preparation of (R)-2-Ethylhexanol and 2-Ethylhexyl laurate.


Ćiško-Anić, Blaženka; Majerić-Elenkov, Maja; Hameršak, Zdenko; Šunjić, Vitomir
Combined Biocatalytic Preparation of (R)-2-Ethylhexanol and 2-Ethylhexyl laurate. // Food technology and biotechnology, 37 (1999), 1; 65-70 (međunarodna recenzija, članak, znanstveni)


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Naslov
Combined Biocatalytic Preparation of (R)-2-Ethylhexanol and 2-Ethylhexyl laurate.

Autori
Ćiško-Anić, Blaženka ; Majerić-Elenkov, Maja ; Hameršak, Zdenko ; Šunjić, Vitomir

Izvornik
Food technology and biotechnology (1330-9862) 37 (1999), 1; 65-70

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Sažetak
(R)-2-Ethylhexanol (R-1) is prepared in high optical purity (>99% enantiomeric excess, e.e.) by the Pseudomonas sp. lipase catalyzed acylation of racemic 1 using vinyl laurate as the acylating agent which allows the isolation of (R)-1 by distillation. Nonactivated lauric acid proved very reactive, affording (R)-1 with >99% e.e., but difficulties in down-stream process disfavored their use. 2-Ethylhexyl laurate (3), the second product in this process, is also commercially valuable material. Recycling of the enzyme and simple isolation of optically pure alcohol (R)-1 makes the method amenable to the scale-up.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
00980701

Ustanove:
Institut "Ruđer Bošković", Zagreb


Citiraj ovu publikaciju:

Ćiško-Anić, Blaženka; Majerić-Elenkov, Maja; Hameršak, Zdenko; Šunjić, Vitomir
Combined Biocatalytic Preparation of (R)-2-Ethylhexanol and 2-Ethylhexyl laurate. // Food technology and biotechnology, 37 (1999), 1; 65-70 (međunarodna recenzija, članak, znanstveni)
Ćiško-Anić, B., Majerić-Elenkov, M., Hameršak, Z. & Šunjić, V. (1999) Combined Biocatalytic Preparation of (R)-2-Ethylhexanol and 2-Ethylhexyl laurate.. Food technology and biotechnology, 37 (1), 65-70.
@article{article, year = {1999}, pages = {65-70}, keywords = {}, journal = {Food technology and biotechnology}, volume = {37}, number = {1}, issn = {1330-9862}, title = {Combined Biocatalytic Preparation of and \#40;R and \#41;-2-Ethylhexanol and 2-Ethylhexyl laurate.}, keyword = {} }
@article{article, year = {1999}, pages = {65-70}, keywords = {}, journal = {Food technology and biotechnology}, volume = {37}, number = {1}, issn = {1330-9862}, title = {Combined Biocatalytic Preparation of and \#40;R and \#41;-2-Ethylhexanol and 2-Ethylhexyl laurate.}, keyword = {} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus





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