engleski

Preparation of Molecularly Imprinted Crosslinked Copolymers by Thermal Degradation of Poly(Methacryl-N, N’ -Diisopropylurea-co-Ethylene Glycol Dimethacrylate)

Crosslinked nanoporous copolymers of methacryl-isopropylamide with ethylene glycol dimethacrylate, poly(MA-iPrA-co-EDMA), were prepared by thermal degradation of crosslinked copolymers of methacryl-diisopropylurea with ethylene glycol dimethacrylate, poly(MA-DiPrU-co-EDMA), at temperature of 180-2500C in vacuum or under TGA conditions in nitrogen. Nonporous copolymers which represent the model compound of nanoporous copolymers of the same structure were also prepared. Both, nanoporous and nonporous model copolymers have almost the same thermal stability as shown by TGA measurements.

Methacryl-N, N’ -diisopropylurea, Poly(Methacryl-N, N’ -diisopropylurea-co-ethylene glycol dimethacrylate), Methacryl-N-isopropylamide, Poly(Methacryl-N-isopropylamide-co-ethylene glycol dimethacrylate), Thermal properties, Thermal degradation

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