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Dual Detection HPSEC System as an Aid in Copolymer Characterization


Tomić, Tatjana; Rogošić, Marko; Matusinović, Zvonimir; Šegudović, Nikola
Dual Detection HPSEC System as an Aid in Copolymer Characterization // New Polymeric Materials, ACS Simposium Series 916 (Chapter 24) / Korugić-Karasz, Ljiljana ; MacKnight, William J. ; Martuscelli, Ezio (ur.).
Wachington: Oxford University Press, American Chemical Society, 2005. str. 325-338


Naslov
Dual Detection HPSEC System as an Aid in Copolymer Characterization

Autori
Tomić, Tatjana ; Rogošić, Marko ; Matusinović, Zvonimir ; Šegudović, Nikola

Vrsta, podvrsta i kategorija rada
Poglavlja u knjigama, znanstveni

Knjiga
New Polymeric Materials, ACS Simposium Series 916 (Chapter 24)

Urednik/ci
Korugić-Karasz, Ljiljana ; MacKnight, William J. ; Martuscelli, Ezio

Izdavač
Oxford University Press, American Chemical Society

Grad
Wachington

Godina
2005

Raspon stranica
325-338

ISBN
0-8412-3928-2

Ključne riječi
Dual detection, copolymers, HPSEC

Sažetak
Compositional heterogeneity is one of the essential factors controlling the physical and physico-chemical properties of copolymers ; its determination is in most cases a rather difficult and challenging scientific task. The overall composition of a copolymer comprising two kinds of repeating units can be determined as a function of molecular mass by the dual detector high performance size exclusion chromatography (HPSEC) technique. The common combination of the refractive index (RI) detector with the UV spectrophotometer can be applied if at least one of the monomer units absorbs at a suitable wavelength and if the UV-spectra of both components are sufficiently different. In this paper, synthesized random copolymers of styrene and methyl methacrylate were dissolved in tetrahydrofurane and characterized by the RI-UV HPSEC technique, at the UV wavelength of 254 nm. Home made software and a corresponding hardware interface were used for the equipment control, data acquisition, data processing and calculation. The obtained results show that the technique is capable for fast, routine determination of average copolymer composition. There is no significant variation of chemical composition with molecular mass for investigated copolymers with lower polystyrene content. For copolymers rich in polystyrene, chemical composition varies with molecular mass. In this case, calculated apparent mass fractions of styrene may exceed 100%.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo

Napomena
Oxford University Press i ACS (American Chemical Society) izdaju seriju publikacija koje se odnose na odabrane simpozije, u ovom slučaju simpozij &#8220 ; ; ; ; New Polymeric Materials&#8221 ; ; ; ; iz 2003.



POVEZANOST RADA


Projekt / tema
0061001
0125019

Ustanove
INA-Industrija nafte d.d.,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb