engleski

Determination of Gibbs energy of transfer of ions across the boundary of two immisicble

The coupled electron and ion transfer was studied at a three-phase arrangement where decamethylferrocene was dissolved in a droplet of nitrobenzene.The fast progression of the reaction starting at the three-phase junction and advancing towards the middle of the droplet is explained on the basis of a simplified model that assumes a progressing activation of the working electrode | nitrobenzene interface due to the ingress of transferred anions and decrease of ohmic resistance inside the nitrobenzene phase.

Gibbs energy; transfer of ions; immisicble solvents; three electrode system

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