engleski

A model of CE mechanism on spherical electrodes

A model of electrode reaction preceded by first-order chemical reaction under chronoamperometric conditions on spherical electrodes is developed. A general solution applying to all values of equilibrium constants, including very small ones, was obtained by numerical integration. Well known analytical solutions for steady-state and near-steady-state conditions and for pure kinetic currents are shown to be special cases of the general solution. The conditions for their application are given.

CE mechanisam; chronoamperometry; spherical electrodes; microelectrodes

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