SYNTHESIS AND PHOTOCHEMISTRY OF STILBENYL-SYDNONES (CROSBI ID 494818)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Butković, Kristina ; Marinić, Željko ; Šindler-Kulyk, Marija
engleski
SYNTHESIS AND PHOTOCHEMISTRY OF STILBENYL-SYDNONES
In continuation of our work on heterocyclic compounds and their photochemical induced intramolecular cycloadditions, the new mesoionic compounds trans-3-{;2-[2-(4-methylphenyl)ethenyl]phenyl}; sydnone(1a), trans-3-{;2-[2-phenylethenyl]phenyl}; sydnone(1b) and trans-3-{;2-[2-(4-methylphenyl)ethenyl]phenylmethyl}; sydnone(2) are synthesized. The sydnone ring is a source of nitrile imine, which might react with the neighboring double bond in intramolecular 1, 3-dipolar cycloaddition giving interesting hetero polycyclic compounds. Upon irradiation, 1a and 1b gave amine and quinoline as main products, formed presumably by an elimination of NO and/or CO via radical intermediate. Irradiation of 2 gave two products, with the same molecular weight, which indicates CO2 elimination and formation of nitrile imine, followed by intramolecular cycloaddition. Structure determination and the mechanism of the photochemical reaction will be discussed
sydnones; stilbenes; photochemistry; synthesis
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Podaci o prilogu
372-x.
2003.
objavljeno
Podaci o matičnoj publikaciji
13th EUROPEAN SYMPOSIUM ON ORGANIC CHEMISTRY: PROGRAMME AND ABSTRACTS
Šunjić, Vitomir
Zagreb:
Podaci o skupu
13th EUROPEAN SYMPOSIUM ON ORGANIC CHEMISTRY
poster
10.09.2003-15.09.2003
Dubrovnik, Hrvatska; Cavtat, Hrvatska