engleski

Influence of glycation on cis/trans isomerization and tautomerization in novel morphiceptin-related Amadori compounds

The influence of N-glycation of the N-terminus on amide bond stereochemistry and tautomeric distribution has been explored via the synthesis and NMR analysis of novel N-(1-deoxy-D-fructos-1-yl) derivatives (Amadori compounds) of the exogenous, milk derived, opioid tetrapeptide morphiceptin.

Amadori; Glycation; Morphiceptin; Cis/trans

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