Tailoring enhanced elasticity of crystalline coordination polymers (CROSBI ID 323244)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Mišura, Ozana ; Pisačić, Mateja ; Borovina, Mladen ; Đaković, Marijana
engleski
Tailoring enhanced elasticity of crystalline coordination polymers
The approach for enhancing the elasticity of crystals with suboptimal elastic performances through a rational design was presented. A hydrogen-bonding link was identified as a critical feature in the structure of the parent material, the Cd(II) coordination polymer [CdI2(I-pz)2]n (I-pz = iodopyrazine), to determine the mechanical output and was modified via cocrystallization. Small organic coformers resembling the initial organic ligand but with readily available hydrogens were selected to improve the identified link, and the extent of strengthening the critical link was in an excellent correlation with the delivered enhancement of elastic flexibility materials.
elastic crystals ; enhancing elasticity ; coordination polymers ; cocrystallization
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Podaci o izdanju
23 (3)
2023.
1318-1322
objavljeno
1528-7483
1528-7505
10.1021/acs.cgd.2c01397