Diamondoid ether clusters in helium nanodroplets (CROSBI ID 323198)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Alić, Jasna ; Messner, Roman ; Alešković, Marija ; Küstner, Florian ; Rubčić, Mirta ; Lackner, Florian ; Wolfgang, E. Ernest ; Šekutor, Marina
engleski
Diamondoid ether clusters in helium nanodroplets
Diamondoid ethers were introduced into superfluid helium nanodroplets and the resulting clusters were analyzed by timeof-flight mass spectrometry. Clusters of higher abundances (magic number clusters) were identified and the corresponding potential cluster geometries were obtained from GFN2-xTB and DFT computations. We found that the studied diamondoid ethers readily self-assemble in helium nanodroplets and that London dispersion attraction between hydrocarbon subunits acts as a driving force for cluster formation. On the other hand, hydrogen bonding between ether oxygens and trace water molecules fosters the eventual breakdown of the initial supramolecular aggregate.
Diamondoids ; He nanodroplets ; London dispersion ; Ethers ; Computational chemistry
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Podaci o izdanju
25
2023.
11951-11958
objavljeno
1463-9076
1463-9084
10.1039/D3CP00489A