engleski

Extending the Hammett correlation to mechanochemical reactions

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical–organic chemistry could be transferable to ball milling reactions in the solid state.

mechanochemistry ; kinetic analysis ; Hammett correlation ; Raman spectroscopy ; imine formation

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