Pregled bibliografske jedinice broj: 124965
Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions
Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions // Croatica chemica acta, 77 (2004), 1-2; 321-324 (međunarodna recenzija, članak, znanstveni)
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Naslov
Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions
Autori
Kazazić, Saša ; Klasinc, Leo ; Rožman, Marko ; Srzić, Dunja ; von Knop, Jan
Izvornik
Croatica chemica acta (0011-1643) 77
(2004), 1-2;
321-324
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
gas phase reaction ; Fourier transform mass spectrometry ; deuterium kinetic isotope effect ; niobium (II) ; pyrene ; pyrene-D10
Sažetak
Analysis of the deuterium isotope effect in the gas phase ligation of Nb+ by pyrene (Pn) whereby a hydrogen molecule is rapidly released from NbPn+ indicates that the effect for the dehydrogenated product formation depends on experimental conditions and amounts 1.2-1.4. A tentative reaction mechanism is proposed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
