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Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions


Kazazić, Saša; Klasinc, Leo; Rožman, Marko; Srzić, Dunja; von Knop, Jan
Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions // Croatica chemica acta, 77 (2004), 1-2; 321-324 (međunarodna recenzija, članak, znanstveni)


Naslov
Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions

Autori
Kazazić, Saša ; Klasinc, Leo ; Rožman, Marko ; Srzić, Dunja ; von Knop, Jan

Izvornik
Croatica chemica acta (0011-1643) 77 (2004), 1-2; 321-324

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Gas phase reaction ; Fourier transform mass spectrometry ; deuterium kinetic isotope effect ; niobium (II) ; pyrene ; pyrene-D10

Sažetak
Analysis of the deuterium isotope effect in the gas phase ligation of Nb+ by pyrene (Pn) whereby a hydrogen molecule is rapidly released from NbPn+ indicates that the effect for the dehydrogenated product formation depends on experimental conditions and amounts 1.2-1.4. A tentative reaction mechanism is proposed.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
0098032

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus