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Pregled bibliografske jedinice broj: 1235666

Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate


Sakač, Nikola; Madunić-Čačić, Dubravka; Marković , Dean; Hok, Lucija; Vianello, Robert; Vrček, Valerije; Šarkanj, Bojan; Đurin, Bojan; Della Ventura , Bartolomeo; Velotta, Raffaele; Jozanović, Marija
Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate // Chemosensors, 10 (2022), 12; 523, 14 doi:10.3390/chemosensors10120523 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 1235666 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate

Autori
Sakač, Nikola ; Madunić-Čačić, Dubravka ; Marković , Dean ; Hok, Lucija ; Vianello, Robert ; Vrček, Valerije ; Šarkanj, Bojan ; Đurin, Bojan ; Della Ventura , Bartolomeo ; Velotta, Raffaele ; Jozanović, Marija

Izvornik
Chemosensors (2227-9040) 10 (2022), 12; 523, 14

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
anionic surfactants ; computational analysis ; green chemistry ; quaternary ammonium compounds ; synthetic ionophore ; potentiometric sensor

Sažetak
As anionic surfactants are used in detergents for cleaning and washing, they pose an environmental and health hazard. A novel potentiometric sensor for anionic surfactants based on the 1, 3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate (DOI-TPB) ionophore is presented. The newly developed approach to DOI-TPB synthesis is faster and simpler than currently used strategies and fol-lows the green chemistry principles. DOI-TPB ionophore was characterized by computational and in-strumental techniques (NMR, LC-MS, FTIR, elemental analysis), and used to produce a PVC-based DOI-TPB sensor. The sensor showed linear response to dodecylbenzenesulfonate and dodecyl sulfate in concentration ranges of 6.3 x 10-7 – 3.2 x 10-4 M and 5.9 x 10-7 – 4.1 x 10-3 M, for DBS and SDS, re-spectively. The sensor shows Nernstian slope (59.3 mV/decade and 58.3 mV/decade for DBS and SDS, respectively), and low detection limits (7.1 x 10-7 M and 6.8 x 10-7 M for DBS and SDS, respectively). DOI-TPB sensor was successfully tested on real samples of commercial detergents and the results were in agreement with the referent methods. Computational analysis underlined the importance of long al-kyl chains in DOI+ and their C–H∙∙∙π interactions with TPB– for the ionophore formation in solution, thereby providing guidelines for the future design of efficient potentiometric sensors.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
IP-2019-04-8846 - In-silico potpomognut dizajn supstrata za hvatanje CO2 u katalitičkoj formaciji karbonata i karbamata (INDICATIOR) (Marković, Dean, HRZZ - 2019-04) ( CroRIS)
HRZZ-IP-2020-02-8090 - Dizajn, sinteza i računalna analiza novih optičkih kemijskih pH osjetilnih derivata benzazola (BenzpHSens) (Vianello, Robert, HRZZ - 2020-02) ( CroRIS)

Ustanove:
Farmaceutsko-biokemijski fakultet, Zagreb,
Institut "Ruđer Bošković", Zagreb,
Geotehnički fakultet, Varaždin,
Sveučilište u Osijeku - Odjel za kemiju,
Sveučilište u Rijeci - Odjel za biotehnologiju,
Sveučilište Sjever, Koprivnica

Poveznice na cjeloviti tekst rada:

Pristup cjelovitom tekstu rada doi www.mdpi.com

Citiraj ovu publikaciju:

Sakač, Nikola; Madunić-Čačić, Dubravka; Marković , Dean; Hok, Lucija; Vianello, Robert; Vrček, Valerije; Šarkanj, Bojan; Đurin, Bojan; Della Ventura , Bartolomeo; Velotta, Raffaele; Jozanović, Marija
Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate // Chemosensors, 10 (2022), 12; 523, 14 doi:10.3390/chemosensors10120523 (međunarodna recenzija, članak, znanstveni)
Sakač, N., Madunić-Čačić, D., Marković , D., Hok, L., Vianello, R., Vrček, V., Šarkanj, B., Đurin, B., Della Ventura , B., Velotta, R. & Jozanović, M. (2022) Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate. Chemosensors, 10 (12), 523, 14 doi:10.3390/chemosensors10120523.
@article{article, author = {Saka\v{c}, Nikola and Maduni\'{c}-\v{C}a\v{c}i\'{c}, Dubravka and Markovi\'{c}, Dean and Hok, Lucija and Vianello, Robert and Vr\v{c}ek, Valerije and \v{S}arkanj, Bojan and \DJurin, Bojan and Della Ventura, Bartolomeo and Velotta, Raffaele and Jozanovi\'{c}, Marija}, year = {2022}, pages = {14}, DOI = {10.3390/chemosensors10120523}, chapter = {523}, keywords = {anionic surfactants, computational analysis, green chemistry, quaternary ammonium compounds, synthetic ionophore, potentiometric sensor}, journal = {Chemosensors}, doi = {10.3390/chemosensors10120523}, volume = {10}, number = {12}, issn = {2227-9040}, title = {Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate}, keyword = {anionic surfactants, computational analysis, green chemistry, quaternary ammonium compounds, synthetic ionophore, potentiometric sensor}, chapternumber = {523} }
@article{article, author = {Saka\v{c}, Nikola and Maduni\'{c}-\v{C}a\v{c}i\'{c}, Dubravka and Markovi\'{c}, Dean and Hok, Lucija and Vianello, Robert and Vr\v{c}ek, Valerije and \v{S}arkanj, Bojan and \DJurin, Bojan and Della Ventura, Bartolomeo and Velotta, Raffaele and Jozanovi\'{c}, Marija}, year = {2022}, pages = {14}, DOI = {10.3390/chemosensors10120523}, chapter = {523}, keywords = {anionic surfactants, computational analysis, green chemistry, quaternary ammonium compounds, synthetic ionophore, potentiometric sensor}, journal = {Chemosensors}, doi = {10.3390/chemosensors10120523}, volume = {10}, number = {12}, issn = {2227-9040}, title = {Potentiometric Surfactant Sensor for Anionic Surfactants Based on 1,3-dioctadecyl-1H-imidazol-3-ium tetraphenylborate}, keyword = {anionic surfactants, computational analysis, green chemistry, quaternary ammonium compounds, synthetic ionophore, potentiometric sensor}, chapternumber = {523} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati:





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