Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8 (CROSBI ID 316764)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Thorne, Michael F. ; Castillo-Blas, Celia ; McHugh, Lauren N. ; Bumstead, Alice M. ; Robertson, Georgina ; Sapnik, Adam F. ; Coates, Chloe S. ; Sayed, Farheen N. ; Grey, Clare P. ; Keen, David A. ; Etter, Martin ; da Silva, Ivan ; Užarević, Krunoslav ; Bennett, Thomas D.
engleski
Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8
he structure of a new ZIF-8 polymorph with quartz topology (qtz) is reported. This qtz-[Zn(mIm)2] phase was obtained by mechanically amorphising crystalline ZIF-8, before heating the resultant amorphous phase to between 282 and 316 °C. The high-temperature phase structure was obtained from powder X-ray diffraction, and its thermal behaviour, CO2 gas sorption properties and dye adsorption ability were investigated.
Mechanochemistry ; MOF ; ZIF-8 ; polymorphism ; amorphous MOFs
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