engleski

Solid-state structure of the homochiral peptide Ac–Pro–Ala–NH–Fn–COOMe

Ferrocene-dipeptide conjugates were found to adopt the turn structures through intramolecular hydrogen bonding as a prerequisite for 3D- structure formation and function of biological systems [1-5]. The chirality and sequence of amino acids are the key factors for constructing chirality-organized bioconjugates [2, 3, 5]. Herein, we report the solid-state properties of compound 1 established by X-ray study and corroborated with DFT calculations.

ferrocene ; peptidomimetics ; conformational analysis ; crystal structure

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