engleski

Impact of Washing Parameters on Thermal Characteristics and Appearance of Proban®—Flame Retardant Material

Proban® is a multiphase treatment of cotton fabrics based on the formation of pre-condensates using the flame retardant (FR) agent tetrakis (hydroxymethyl) phosphonium salts (THPx). The assessment of the durability of a product demands a preliminary understanding of how relevant it is to extend its lifetime. It is therefore important to minimize the risk of agents impacting: (1) the protection level, (2) shape and dimensions, and (3) additional comfort characteristics of the fabric. This research focused on the impact of washing conditions on the durability of FR properties and appearance of Proban® cotton fabrics, which was systematically arranged through the variation in the chemistry distribution in the Sinner’s circle. The chemical share was varied in laboratory conditions as a simulation of industrial washing based on component dosing, where the temperature, time and mechanical agitation were constant. The washing of cotton fabrics was performed through 10 cycles in four baths containing high alkali components, medium alkali components, high alkali reference detergent and water. The environmental acceptability of washing procedures through effluent analysis was assessed by physico–chemical and organic indicators. The limited oxygen index (LOI), calorimetric parameters (micro combustion calorimetry), thermal stability and evolved gases during thermal decomposition (thermogravimetric analyzer (TGA) coupled with an infrared spectrometer (TG–IR)), surface examination (FE- SEM), spectral characteristics and pH of the aqueous extract of the fabrics before and after 10 washing cycles were selected for proof of durability. The medium alkali bath was confirmed as a washing concept for Proban® cotton fabric through the preservation of FR properties examined through LOI, TGA, TG–IR and MCC parameters and appearance color and low level of fibrillation.

cotton fabric ; Proban® ; environmentally friendly washing procedure ; flame retardant durability ; MCC ; appearance

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