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Pregled bibliografske jedinice broj: 1210003

Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism


Stolar, Tomislav; Alić, Jasna; Lončarić, Ivor; Etter, Martin; Jung, Dahee; Farha, K. Omar; Đilović, Ivica; Meštrović, Ernest; Užarević, Krunoslav
Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism // Crystengcomm, 24 (2022), 6505-6511 doi:10.1039/D2CE00668E (međunarodna recenzija, članak, znanstveni)


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Naslov
Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism

Autori
Stolar, Tomislav ; Alić, Jasna ; Lončarić, Ivor ; Etter, Martin ; Jung, Dahee ; Farha, K. Omar ; Đilović, Ivica ; Meštrović, Ernest ; Užarević, Krunoslav

Izvornik
Crystengcomm (1466-8033) 24 (2022); 6505-6511

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
mechanochemistry ; HOFs ; polymorphism

Sažetak
With an increasing need to make preparative chemistry more sustainable, mechanochemistry receives much attention. It is attractive for synthesizing open coordination or covalent frameworks, offering an unprecedented level of synthetic control while reducing solvent usage and frequently accessing products not available by conventional synthetic methods. Here, we present sustainable solid form screening of 2, 6-diaminopurine (DAP) nucleobase, an important hydrogen-bonded framework building block. DAP is well known for treating genetic diseases and occurring as a nucleobase in viral DNA, yet its solid-state chemistry is unknown. With a total solvent consumption of 0.6 mL, we discovered five new DAP solid forms by mechanochemical and thermal routines, including a polymorphic pair of DAP hydrogen-bonded organic frameworks (HOFs). Two DAP-HOF polymorphs formed selectively by choosing the liquid additive in liquid-assisted grinding (LAG). Monitoring by in situ Raman spectroscopy revealed different formation profiles for each DAP-HOF polymorph, and nitrogen adsorption isotherms confirmed their permanent porosities. The density functional theory (DFT) analysis established the relative thermodynamic stability of crystallographically characterized DAP solid forms. Our results demonstrate the ability of mechanochemistry to control HOF polymorphism, which might be critical for their properties and subsequent applications. In a broader perspective, this work opens the door for sustainable studies on nucleobase-inspired HOF materials.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-PZS-2019-02-4129 - Mehanokemijske i bezotopinske strategije za sintezu funkcionalnih poroznih materijala s naprednim fizičko-kemijskim i katalitičkim svojstvima (MECHADVANCE) (Užarević, Krunoslav, HRZZ - 2019-02) ( CroRIS)
HRZZ-IP-2020-02-4702 - Važnost mehanokemijske reaktivnosti u prebiotičkoj kemijskoj evoluciji i njezin prijenos na održivu kemijsku proizvodnju s niskim emisijama (PREBIOMECHEM) (Užarević, Krunoslav, HRZZ - 2020-02) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Poveznice na cjeloviti tekst rada:

doi pubs.rsc.org doi.org

Citiraj ovu publikaciju:

Stolar, Tomislav; Alić, Jasna; Lončarić, Ivor; Etter, Martin; Jung, Dahee; Farha, K. Omar; Đilović, Ivica; Meštrović, Ernest; Užarević, Krunoslav
Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism // Crystengcomm, 24 (2022), 6505-6511 doi:10.1039/D2CE00668E (međunarodna recenzija, članak, znanstveni)
Stolar, T., Alić, J., Lončarić, I., Etter, M., Jung, D., Farha, K., Đilović, I., Meštrović, E. & Užarević, K. (2022) Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism. Crystengcomm, 24, 6505-6511 doi:10.1039/D2CE00668E.
@article{article, author = {Stolar, Tomislav and Ali\'{c}, Jasna and Lon\v{c}ari\'{c}, Ivor and Etter, Martin and Jung, Dahee and Farha, K. Omar and \DJilovi\'{c}, Ivica and Me\v{s}trovi\'{c}, Ernest and U\v{z}arevi\'{c}, Krunoslav}, year = {2022}, pages = {6505-6511}, DOI = {10.1039/D2CE00668E}, keywords = {mechanochemistry, HOFs, polymorphism}, journal = {Crystengcomm}, doi = {10.1039/D2CE00668E}, volume = {24}, issn = {1466-8033}, title = {Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism}, keyword = {mechanochemistry, HOFs, polymorphism} }
@article{article, author = {Stolar, Tomislav and Ali\'{c}, Jasna and Lon\v{c}ari\'{c}, Ivor and Etter, Martin and Jung, Dahee and Farha, K. Omar and \DJilovi\'{c}, Ivica and Me\v{s}trovi\'{c}, Ernest and U\v{z}arevi\'{c}, Krunoslav}, year = {2022}, pages = {6505-6511}, DOI = {10.1039/D2CE00668E}, keywords = {mechanochemistry, HOFs, polymorphism}, journal = {Crystengcomm}, doi = {10.1039/D2CE00668E}, volume = {24}, issn = {1466-8033}, title = {Sustainable solid form screening: mechanochemical control over nucleobase hydrogen-bonded organic framework polymorphism}, keyword = {mechanochemistry, HOFs, polymorphism} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati:





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