engleski

Band Gap Engineering in Novel Fluorite-Type Rare Earth High-Entropy Oxides (RE-HEOs) with Computational and Experimental Validation for Photocatalytic Water Splitting Applications

Five different rare-earth-based high entropy oxides (HEOs) nanoparticles with fluorite type of structure and average crystallite sizes between 6 and 9 nm are prepared and their photocatalytic behaviour towards AZO dye degradation and photoelectrochemical water splitting for hydrogen generation is examined. The cationic site in the fluorite lattice consists of five equimolar elements selected from the group of rare-earth elements including La, Ce, Pr, Eu, and Gd and second-row transition metals, Y and Zr. Studied HEOs exhibit bandgaps in the range from 1.91 eV to 3.0 eV and appropriate valence and conduction bands for water splitting. They reveal high photocatalytic activity that is mostly attributed to the accessibility of more photocatalytic active sites which provided radicals responsible for the AZO dye degradation. The material successfully produces hydrogen by photocatalytic water splitting, suggesting the potential of HEOs as new photocatalysts. The photocatalytic performances of all studied HEOs outperform the single fluorite oxides or equivalent mixed oxides. The Ce0.2Zr0.2La0.2Pr0.2Y0.2O2 engender hydrogen in 9.2 µmolmg–1 per hour that is much higher content than for pristine CeO2 material which amounts to 0.8 µmolmg–1 per hour.

High-entropy oxides, photocatalysis, hydrogen, hydrogen evolution reaction

nije evidentirano