Sol-gel synthesis of ceria-zirconia-based high- entropy oxides as high-promotion catalysts for the synthesis of 1,2-diketones from aldehyde (CROSBI ID 718638)
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Podaci o odgovornosti
Djerdj, Igor ; Tatar, Dalibor ; Kojčinović, Jelena ; Marković, Berislav ; Széchenyi, Aleksandar ; Miletić, Aleksandar ; Nagy, Sandor ; Ziegenheim, Szilvester ; Szenti, Imre ; Sapi, Andras ; Kukovecz, Akos ; Tang, Yushu ; Stenzel, David ; Varga, Gabor
engleski
Sol-gel synthesis of ceria-zirconia-based high- entropy oxides as high-promotion catalysts for the synthesis of 1,2-diketones from aldehyde
Efficient Lewis-acid-catalyzed direct conversion of aldehydes to 1, 2-diketones in the liquid phase was enabled by using newly designed and developed ceria–zirconia-based high-entropy oxides (HEOs) as the actual catalysts. The synergistic eàect of various cations incorporated in the same oxide structure (framework) was partially responsible for the efficiency of multicationic materials compared to the corresponding single cation oxide forms. Furthermore, a clear, linear relationship between the Lewis acidity and the catalytic activity of the HEOs was observed. Due to the developed strategy, exclusively diketone- selective, recyclable, versatile heterogeneous catalytic transformation of aldehydes can be realized under mild reaction conditions.
Lewis acid ; catalyst ; high entropy ; oxides ; aldehyde ; diketone
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Podaci o prilogu
n/a
2022.
objavljeno
Podaci o matičnoj publikaciji
Podaci o skupu
ACS National Meeting and Exposition Spring 2022: Bonding Through Chemistry
poster
20.03.2022-24.03.2022
San Diego (CA), Sjedinjene Američke Države