Thermal Degradation and Kinetic Analysis of Multi- layered Plastics (CROSBI ID 716837)
Prilog sa skupa u zborniku | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Kremer, Irma ; Tomić, Tihomir ; Katančić, Zvonimir ; Hrnjak-Murgić, Zlata ; Erceg, Matko ; Schneider, Daniel Rolph
engleski
Thermal Degradation and Kinetic Analysis of Multi- layered Plastics
Multi-layered plastics are a great challenge for the waste recycling industry. The majority of multi-layered plastics consist of two or more types of polymers, making it difficult to recycle mechanically, which leads to landfill or incineration plant. As a way of thermochemical recycling, pyrolysis is a promising cleaner technology that could use multi-layered waste plastics potential and convert it into valuable products like fuels and chemicals. To better understand the pyrolysis process of multi-layered plastics, thermogravimetric analysis was carried out to determine their thermochemical behaviour and kinetic parameters. Thermogravimetric measurements were conducted in a nitrogen atmosphere at heating rates of 5, 10, 15 and 20 °C/min in the temperature range 40−600 °C. Kinetic analysis was done using the isoconversional model- free Friedman method in combination with an advanced statistical approach. Thermogravimetric analysis revealed how decomposition occurs in the range 350−510 °C and the weight loss >90% indicating high volatile matter content, hence potential for pyrolytic oil production. The results of the kinetic analysis showed how pyrolysis of multi-layered plastics is a complex process consisting of three decomposition stages. The activation energy values determined by Friedman were rising with the degree of conversion from 127 kJ/mol at 0.01 to 219 kJ/mol at 0.95.
Multi-layered plastics ; thermochemical recycling ; pyrolysis ; dynamic thermogravimetric analysis ; kinetic study
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Podaci o prilogu
1-12.
2021.
objavljeno
Podaci o matičnoj publikaciji
Digital Proceedings of 16th Conference on Sustainable Development of Energy, Water and Environment Systems
Ban, Marko
Zagreb: Fakultet strojarstva i brodogradnje Sveučilišta u Zagrebu
Podaci o skupu
16th Conference on Sustainable Development of Energy, Water and Environment Systems (SDEWES)
predavanje
10.10.2021-15.10.2021
Dubrovnik, Hrvatska