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Pregled bibliografske jedinice broj: 1190118

Thermal Degradation and Kinetic Analysis of Multi- layered Plastics


Kremer, Irma; Tomić, Tihomir; Katančić, Zvonimir; Hrnjak-Murgić, Zlata; Erceg, Matko; Schneider, Daniel Rolph
Thermal Degradation and Kinetic Analysis of Multi- layered Plastics // Digital Proceedings of 16th Conference on Sustainable Development of Energy, Water and Environment Systems / Ban, Marko (ur.).
Zagreb: Faculty of Mechanical Engineering and Naval Architecture, 2021. str. 1-12 (predavanje, međunarodna recenzija, cjeloviti rad (in extenso), znanstveni)


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Naslov
Thermal Degradation and Kinetic Analysis of Multi- layered Plastics

Autori
Kremer, Irma ; Tomić, Tihomir ; Katančić, Zvonimir ; Hrnjak-Murgić, Zlata ; Erceg, Matko ; Schneider, Daniel Rolph

Vrsta, podvrsta i kategorija rada
Radovi u zbornicima skupova, cjeloviti rad (in extenso), znanstveni

Izvornik
Digital Proceedings of 16th Conference on Sustainable Development of Energy, Water and Environment Systems / Ban, Marko - Zagreb : Faculty of Mechanical Engineering and Naval Architecture, 2021, 1-12

Skup
Conference on Sustainable Development of Energy, Water and Environment Systems

Mjesto i datum
Dubrovnik, Hrvatska, 10-15.10.2021

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Multi-layered plastics ; thermochemical recycling ; pyrolysis ; dynamic thermogravimetric analysis ; kinetic study

Sažetak
Multi-layered plastics are a great challenge for the waste recycling industry. The majority of multi-layered plastics consist of two or more types of polymers, making it difficult to recycle mechanically, which leads to landfill or incineration plant. As a way of thermochemical recycling, pyrolysis is a promising cleaner technology that could use multi-layered waste plastics potential and convert it into valuable products like fuels and chemicals. To better understand the pyrolysis process of multi-layered plastics, thermogravimetric analysis was carried out to determine their thermochemical behaviour and kinetic parameters. Thermogravimetric measurements were conducted in a nitrogen atmosphere at heating rates of 5, 10, 15 and 20 °C/min in the temperature range 40−600 °C. Kinetic analysis was done using the isoconversional model- free Friedman method in combination with an advanced statistical approach. Thermogravimetric analysis revealed how decomposition occurs in the range 350−510 °C and the weight loss >90% indicating high volatile matter content, hence potential for pyrolytic oil production. The results of the kinetic analysis showed how pyrolysis of multi-layered plastics is a complex process consisting of three decomposition stages. The activation energy values determined by Friedman were rising with the degree of conversion from 127 kJ/mol at 0.01 to 219 kJ/mol at 0.95.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo



POVEZANOST RADA


Projekti:
HRZZ-IP-2018-01-3200 - Napredni nositelji energije u oporabi plastičnog otpada (NEOPLAST) (Schneider, Daniel Rolph, HRZZ - 2018-01) ( POIROT)

Ustanove:
Kemijsko-tehnološki fakultet, Split,
Fakultet strojarstva i brodogradnje, Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb


Citiraj ovu publikaciju:

Kremer, Irma; Tomić, Tihomir; Katančić, Zvonimir; Hrnjak-Murgić, Zlata; Erceg, Matko; Schneider, Daniel Rolph
Thermal Degradation and Kinetic Analysis of Multi- layered Plastics // Digital Proceedings of 16th Conference on Sustainable Development of Energy, Water and Environment Systems / Ban, Marko (ur.).
Zagreb: Faculty of Mechanical Engineering and Naval Architecture, 2021. str. 1-12 (predavanje, međunarodna recenzija, cjeloviti rad (in extenso), znanstveni)
Kremer, I., Tomić, T., Katančić, Z., Hrnjak-Murgić, Z., Erceg, M. & Schneider, D. (2021) Thermal Degradation and Kinetic Analysis of Multi- layered Plastics. U: Ban, M. (ur.)Digital Proceedings of 16th Conference on Sustainable Development of Energy, Water and Environment Systems.
@article{article, author = {Kremer, Irma and Tomi\'{c}, Tihomir and Katan\v{c}i\'{c}, Zvonimir and Hrnjak-Murgi\'{c}, Zlata and Erceg, Matko and Schneider, Daniel Rolph}, editor = {Ban, M.}, year = {2021}, pages = {1-12}, keywords = {Multi-layered plastics, thermochemical recycling, pyrolysis, dynamic thermogravimetric analysis, kinetic study}, title = {Thermal Degradation and Kinetic Analysis of Multi- layered Plastics}, keyword = {Multi-layered plastics, thermochemical recycling, pyrolysis, dynamic thermogravimetric analysis, kinetic study}, publisher = {Faculty of Mechanical Engineering and Naval Architecture}, publisherplace = {Dubrovnik, Hrvatska} }
@article{article, author = {Kremer, Irma and Tomi\'{c}, Tihomir and Katan\v{c}i\'{c}, Zvonimir and Hrnjak-Murgi\'{c}, Zlata and Erceg, Matko and Schneider, Daniel Rolph}, editor = {Ban, M.}, year = {2021}, pages = {1-12}, keywords = {Multi-layered plastics, thermochemical recycling, pyrolysis, dynamic thermogravimetric analysis, kinetic study}, title = {Thermal Degradation and Kinetic Analysis of Multi- layered Plastics}, keyword = {Multi-layered plastics, thermochemical recycling, pyrolysis, dynamic thermogravimetric analysis, kinetic study}, publisher = {Faculty of Mechanical Engineering and Naval Architecture}, publisherplace = {Dubrovnik, Hrvatska} }




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