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Pregled bibliografske jedinice broj: 117506

Macrocyclic vs. acyclic derivatives of chiral bis(oxazolines) ; ligand distortion and enantioselectivity of Pd(II) complexes in catalytic allylic alkylation


Šepac, Dragan; Marinić, Željko; Portada, Tomislav; Žinić, Mladen; Šunjić, Vitomir
Macrocyclic vs. acyclic derivatives of chiral bis(oxazolines) ; ligand distortion and enantioselectivity of Pd(II) complexes in catalytic allylic alkylation // Tetrahedron, 59 (2003), 8; 1159-1167 (međunarodna recenzija, članak, znanstveni)


Naslov
Macrocyclic vs. acyclic derivatives of chiral bis(oxazolines) ; ligand distortion and enantioselectivity of Pd(II) complexes in catalytic allylic alkylation

Autori
Šepac, Dragan ; Marinić, Željko ; Portada, Tomislav ; Žinić, Mladen ; Šunjić, Vitomir

Izvornik
Tetrahedron (0040-4020) 59 (2003), 8; 1159-1167

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Enantioselectivity; allylic alkylation; Pd(II) complex; 1; 5-(bis)oxazoline

Sažetak
Pd(II) complexes of acyclic (1, 2 ; 4, 5) and macrocyclic (3, 6-10) derivatives of 1, 5-bis(oxazolines), are tested in the enantioselective allylic alkylation of racemic 1, 3-diphenyl-3-acetoxyprop-2-ene (14) by dimethylmalonate anion to allyl malonate derivative 15. Conformation in solution of representative allyl Pd(H) complexes 12 and 13 is studied by 2D NMR and CD spectroscopy. 2D NMR data reveal loss of C-2 symmetry of the ligands in Pd(II)allyl-bis(oxazoline) complexes. CD spectra indicate distortion of the bidentate ligand in the complex and a conformationally forced larger twist between two chromophores in the macrocyclic complex. Only moderate variation of enantioselectivity with the length and ring size of the ligand is observed, and a rationale offered.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Biologija



POVEZANOST RADA


Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Uključenost u ostale bibliografske baze podataka:


  • Chemical Abstracts