N-(4-halogenobenzyl)-(3-halogeno)pyridinium cations as halogen bond donors (CROSBI ID 712340)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | domaća recenzija
Podaci o odgovornosti
Fotović, Luka ; Bedeković, Nikola ; Stilinović, Vladimir
engleski
N-(4-halogenobenzyl)-(3-halogeno)pyridinium cations as halogen bond donors
Halogen bond is a valuable widely used tool for constructing supramolecular assemblies in the solid state.[1] Besides numerous studies on neutral halogen bond donors, [2] a few studies dealing with cationic halogen bond donors such as halogenopyridinium cations have been published. [3, 4] In our previous work we have shown that halogen bonds in protonated iodopyridinium halogenides can even compete with hydrogen bond in binding halogenide anions.[5] In this study, we have been interested in asymmetric ditopic monocationic halogen bond donor where one halogen bond donor atom is placed on positively charged pyridine ring while other one on “neutral” benzyl ring (the positive charge is mostly located on the pyridine nitrogen ring). We successfully prepared a series of six N-(4- halogenobenzyl)-(3- halogeno)pyridinium bromides. To study the halogen bonding potential of these cations with a wider range of (anionic) halogen bond acceptors the chloride and iodide salts were prepared by ion exchange. Single crystal X-ray diffraction experiments revealed that in these systems the halogen bonds with the halogen atoms on pyridinium rings with halogenide anions are generally relatively shorter (as compared to the corresponding van der Waals radii) than the halogen bonds with the halogen atoms on the “neutral” part of cations (benzyl ring).
pyridinium cations ; halogen bond ; halogenide anions
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Podaci o prilogu
186-186.
2021.
objavljeno
Podaci o matičnoj publikaciji
27th Croatian Meeting of Chemists and Chemical Engineers and 5th Symposium Vladimir Prelog : Book of Abstracts
Marković, Dean ; Meštrović, Ernest ; Namjesnik, Danijel ; Tomašić, Vesna
Zagreb: Hrvatsko kemijsko društvo
2757-0754
Podaci o skupu
27. hrvatski skup kemičara i kemijskih inženjera (27HSKIKI)
poster
05.10.2021-08.10.2021
Veli Lošinj, Hrvatska