engleski

Model of reactant adsorption in dc polarography

An expanding plane model of polarogram influenced by the reactant adsorption is developed and applied to the Frumkin isotherm. It is shown that the polarogram may consist of the main wave and post-wave that are separated by the maximum and minimum. The origin of these extremes are investigated by the calculation of currents that flow during a single mercury drop.

Adsorption of reactant ; Dc polarography ; Expanding plane model.

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