Magnetic properties of mixed copper/zinc MOF-74 compounds and their amorphous phases (CROSBI ID 710226)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa
Podaci o odgovornosti
Žilić, Dijana ; Muratović, Senada ; Karadeniz, Bahar ; Martinez, Valentina ; Užarević, Krunoslav ; Pajić, Damir ; Krupskaya, Yilia ; Kataev, Vladislav
engleski
Magnetic properties of mixed copper/zinc MOF-74 compounds and their amorphous phases
Here we present the results of the study of magnetic properties of copper(II)-MOF-74 materials (Cu-MOF-74) and their three mixed analogues with zinc(II). CuZn-MOF-74 and ZnCu-MOF-74 were obtained through different intermediate complexes, namely from magnetically also interesting Cu-INT or from non-magnetic Zn-INT, respectively. The alloyed Cu-MOF-74-Zn-MOF-74 was obtained by growing the MOF structure from the mixture of milled Cu-MOF-74 and Zn-MOF-74 exposed to solvent vapors (accelerated ageing).[1] Additionally, we investigated how the amorphization process influences the magnetic properties of studied crystalline copper/zinc MOF-74 compounds.[2] Magnetic characterization was obtained by static magnetization measurements, X-band electron spin resonance (ESR) spectroscopy as well as multifrequency high-field high-frequency ESR (HF- ESR) spectroscopy. [1] G. Ayoub et al, Chem. Mater. 31 (2019) 5494. [2] S. Muratović et al, J. Mater. Chem. C 8 (2019) 7132.
MOF ; Cu-MOF-74 ; ESR
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Podaci o prilogu
63-111.
2021.
objavljeno
Podaci o matičnoj publikaciji
Solid-State Science & Research 2021 : Book of Abstracts and Programme
Biliškov, Nikola ; Brekalo, Ivana ; Martinez, Valentina
Zagreb: Institut Ruđer Bošković
978-953-7941-35-2
Podaci o skupu
Solid-State Science & Research 2021 (SCIRES2021)
poster
10.07.2021-11.07.2021
Zagreb, Hrvatska