engleski

Product inhibited enzymatic reactions on the rotating disk electrodes

A model of cyclic staircase voltammetry of enzymatic reactions on the rotating disk electrode is developed and the inhibition by the product is investigated. The responses are mostly time - dependent current - potential curves with maxima in the forward but not in the backward branch. If the maxima appear in both branches, the inhibition is potential - dependent either directly or indirectly. The source of the second maximum is explained.

Maxima under steady-state ; Cyclic staircase voltammetry ; Digital simulation ; Transient current.

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